Factors of Concentration of Chalcophile Elements in the Evolution of Plateau-Basaltic Magmas

Authors

  • A. P. Vinogradov Institute of Geochemistry, Siberian Branch of the USSR Academy of Sciences, Irkutsk 664033

Abstract

The geochemical evolution of ore-bearing trappean intrusions particularly from the Siberian platform is discussed. Analysis of empirical geochemical and experimental data shows, on the one hand, that it is reasonable to suggest that chalcophile elements were concentrated together with the sulfide melt in the lower horizons of the bedded bodies due to gravitational accumulation of the sulfide melt and, on the other hand, that the mechanism of sulfurization of basic magmas is the most possible one to explain the formation of sulfide liquid in sufficient quantities to concentrate ore components in economic amounts.

Within the framework of the hypothesis of magmatic sulphurization, the source of ore elements is the parental magma. The source of sulfur seems to be of crustal nature. Since the sulfide melt formed after the sulfurization mechanism is in equilibrium with the silicate part of the system, it does not differ from the sulfide melt formed due to liquation of the sulfur dissolved in the magma. There are as yet no data enough for a quantitative estimation of the contribution from the sulfide-silicate liquation which is, undoubtedly, manifested steadily. However, it may be stated that the role of sulfide-liquid liquation in the ore genesis is negligible.

In terms of the above mechanism, the conditions necessary for chalcophile elements to be concentrated at the magmatic stage in ore amounts are estimated: 1. Primary enrichment of ore elements in magma at the pre-chamber stage effected by the formation of magnesian melts. 2. The contact of the intruding melt with sulfur-containing sequences. 3. Deep differentiation of the intruding melt to facilitate gravitational accumulation of sulfide liquid.

Downloads

Download data is not yet available.

Issue

Section

Research Papers

Published

1980-02-01

How to Cite

Al’ Mukhamedov, A. I. (1980). Factors of Concentration of Chalcophile Elements in the Evolution of Plateau-Basaltic Magmas. Journal of Geological Society of India, 21(2), 57–74. Retrieved from https://geosocindia.com/index.php/jgsi/article/view/64665

References

AL'MUKHAMEDOV. A. I, (1969) Geochemistry of rare elements in traps of the Siberian Platform in connection with the problem of genesis of copper-nickel deposits. 'Akad. Nauk SSSR Doklady ', v, 186, no. 3. pp. 686-689 (in Russian).

AL'MUKHAMEDOV. A. I, (1972) Some peculiarities in pre-chamber differentiation of basaltic-magma (Exemplified' by Siberian traps). 'Geologiya and Geofizika ", no. 1, pp. 43-52 (in Russian).

AL'MUKHAMEDOV. A. I, (1973) Geochemistry of titanium in formation processes of layered intrusions of basic composition (on the example of differentiated traps of Siberian Platform). In: Geochemistry of Rare Elements in Basic and Ultrabasic Complexes of Eastern Siberia, Moscow, "Nauka", pp. 110-151 (in Russian).

AL'MUKHAMEDOV. A. I, (1974) On the geochemistry of sulphur in processes of silicate melt evolution. ' Geokhimiya '; no. 1, pp. 56-62 (in Russian). (Engl translation, see in: 'Geochem. Intern.', 1974, v. 11, no. 1, pp. 42-47).

AL'MUKHAMEDOY, A. I. and MEDVEDEV, A. YA., (1977) Sulfurization is one of possible ways of formation of sulfide copper-nickel deposits. 'Akad. Nauk SSSR Doklady', v, 236, no. 4, pp. 965-968 (in Russian).

AL'MUKHAMEDOY, A. I. and MEDVEDEV, A. YA., (1977) Sulfur in basic and ultrabasic melts as related to the problem of formation of copper-nickel deposits (on experimental data). In: Problems of Geochemistry of Endogenic Processes. Novosibirsk,' Nauka'; pp. 267-278 (in Russian).

AL'MUKHAMEDOV, A. L., MEDVEDEV, A. YA., SOLOMONOYA, L. A. and TAROEV, V. K., (1974) The solubility of sulfur in basic silicate melts and some geochemical considerations. "Geokhimiya", no. 11, pp. 1672-1681 (in Russian. Engl. translation see in: 'Geochem'. Intern.", 1975, v. 11, no. 6, pp. 1178-1186).

AL'MUKHAMEOOY, A. I. and NESTERENKO, G. V., (1970) On two maxim of sulfide minerals. content in differentiated traps of the Siberian Platform. "Geologiya and Geofizika", no. 7, pp. 79-82 (in Russian).

AL'MUKHAMEDOV, A. I. and PETROV, L. L., (1978) Fluorine, boron and beryllium in traps of the Siberian Platform. "Geokhimiya ", no. 7, pp. 979-990 (in Russian).

AL'MUKHAMEDOV, A. I., SMIRNOVA, N. P. and KORNAKOV, Yu. N., (1972) Possible role of diffusion in differentiation processes of basaltic magma in situ. 'Geologiya and Geofizika' , no. 3, pp. 38-47 (in Russian).

ANFILOGOV, V. N., (1973) The equilibrium polycondensation and the structure of silicate melts. "Geokhimiya", no. 2, pp. 1793-1800 (in Russian).

ANFILOGOV, V. N. and AL'MUKHAMEDOV, (1970) Differentiation of silicate melts from the point of view of chemical radical polymerization. "Geokhimiya", no. 5, pp, 552-561.

ARKHIPOVA, A. I. and NACHINKIN, N. G., (1963) Nizhnefokinskaya differentiated intrusion in the Northwest of Siberian Platform (right bank of Enisey river). In: Proceedings of Scientific Research Institute of the Geology of the Arctic, v. 133, no. 1, pp. 51-61 (in Russian).

CONNOLLY, J. W. D. and HOUGHTON, D. R., (1972) The valence of sulfur in glass of basaltic composition formed under conditions of low oxidation potential. 'Amer. Miner.', v. 57, no. 9-10, pp. 1515-1517.

FFOKTISTOV, G. D., (1965) The trap intrusion types in the Southern part of Siberian Platform. In: Petrography of the Eastern Siberia, v. 3, Moscow, "Nauka", pp. 113-167 (in Russian).

FINCHAM, C. J. B. and RICHARDSON, F. D., (1954) The behaviour of sulfur in silicate and aluminate melts. ' Proc, Roy. Soc.', v. 223, no. 1152, pp. 40-62.

GODLEVSKIY, M. N., (1959) Traps and ore-bearing intrusions of Norilsk region, Moscow, "Gosgeoltekhizdat ", p. 68. (in Russian).

GRINENKO, V. A., DMITRIEV, L. V., MIGDISOV, A. A. and SHARASKIN. A. YA., (1975) Content and isotopic composition of sulfur in magmatic and metamorphic rocks of mid-oceanic ridges. "Geokhimiya", no. 2, pp. 199-206 (in Russian).

GRINENKO, V. A. and GRINENKO, L. N., (1974) Geochemistry of sulfur isotopes, Moscow., 'Nauka', p. 274 (in Russian).

HAUGHTON, D. R., ROEDER, P. L. and SKINNER, B. J., (1974) Solubility of sulfur in mafic magmas. Econ. Geol.'; v. 69, no. 4, pp. 451-467.

KATSURA, T. and NAGASHIMA. S., (1974) Solubility of sulfur in some magmas at 1 atmosphere. 'Geochim. et Cosmochim. Acta', v. 38, no. 4, pp 517-531.

KORNAKOV, Yu, N., NESTERENKO, G. V. and SMIRNOVA, N. P., (1965) Petrography of Kaierkan intrusion of traps and peculiarities of distribution of some trace elements in it. In:' Problems of Geochemistry of Igneous Rocks and Ore Deposits of Eastern Siberia, Moscow, 'Nauka ', pp. 165-180 (in Russian).

KOTUL'SKIY, V. K., (1946) On the origin of magmatic copper-nickel deposits. 'Akad. Nauk SSSR Doklady'; v. 51, no. 5, pp, 381-383 (in Russian).

KRAVTSOVA, L. I., (1966) Regularities of evolutipn of trap magmatism of Kureika region (NorthWest of Siberian Platform). In: Geology and petrology of Intrusive Traps of Siberian Platform. Moscow, 'Nauka ', pp. 43-65 (in Russian).

KULLERUD, G. A. and YODER, H. S., (1965) Sulfide-silicate reactions and their bearing on ore formation under magmatic, postmagmatic and metamorphic conditions. In: Symposium Problems of Postmagmatic Ore Deposition'. v. 2, Prague, pp. 327-331.

KUZNETSOVA, S. YA. and KRIOMAN, L. D., (1978) Sulfur solubility in silicate melts are models of natural magmas. "Geokhimiya " no. 2, pp. 238-247 (in Russian).

LEBEDEV, A. P., (1957) Differentiation types in trappean rocks of the Siberian Platform. "Akad, Nauk SSSR lzvestiya ", Ser. Geol., no. 2, pp. 55-74 (in Russian).

LIBAUDE, J., (1975) Quelques observations sur 'extraction s'elative du nickel an cours de la sulfuration des silicates. 'C.R. Acad. Sci.', D280, no. 13, pp. 1513-1515.

LIKHACHEV, A. P., (1978) On the conditions of formation of ore-bearing and ore-free magmas of the basite-ultrabasite composition. 'Akad. Nauk SSSR Doklady ', v. 238, no. 8, pp. 447-450 (in Russian).

LIKHACHEV, A.P. and KUKOEV, V. A., (1973) on the melting and phase relation in sulfide, silicate, and sulfide-silicate systems. 'Geologiya rudnykh mestorozhdeniy', v, 15, no. 5, pp. 32-45 (in Russian).

LIKHACHEV, A. P. and STRIZHOV, V. P., (1974) On the sulfur isotopic composition changes of sulfide copper-nickel deposits at heating and hydrothermal recrystallization. ' Zapiski Vsesoyusn. Mineralog, Ob.'; pt. 103, no. 3, pp. 305-312 (in Russian).

Macroe, N. D., (1974) Sulfurization of basalt under thermal metamorphic conditions to produce cordierite-bearing rocks. Canad. Jour. Earth Sciences. v, 11, no. 2, pp. 246-253.

MAINWARING, P. R. and NALDRETT, A. J., (l977) Country-rocks assimilation and the genesis of Cu-Ni sulfides in the Water Hen intrusion, Duluth complex, Minnesota. Econ. Geot., v. 72, no. 7, pp. 1269-1284.

MASAITIS, V. L., (1958) Petrology of Alamdzhak trap intrusion (the river Vilyui basin), Leningrad, Gosgeoltekhizdat ", (Proc, of All-Union Geological Institute, new series, no, 22), p. 135 (in Russian)

MEDEVEDEV, A. YA. and AL'MUKHAMEDOV A. I., (1978) Distribution of chalcophile elements among the sulfide and silicate fusions (according to the experimental data). ' Akad Nauk SSSR Doklady '; v. 240, no. 3, pp. 718-721 (in Russian).

MIRONOV, A. G., AL'MUKHAMEDOV, A. I., KRENDELEV, F. P. and. MEDVEDEN, A. YA., (1977) Investigation of gold distribution between phases of the basaltic system by means of 195Au radioactive isotope. Akad. Nauk SSSR Doklady', v. 236, no. 6, pp. 1461-1463 (in Russian).

NALDRETT, A. J., (l966) The role of sulfurization in the genesis of iron-nickel sulfide deposits of the Porcupine district, Ontario. 'Canad. Mining Metall. Bull., v, 59, no. 648, pp. 489-497.

NATORKHIN, I. A., ARKHIPOVA,A. J. and BATUEV, B. N., (1977) Petrology of Talnakh intrusions. Leningrad, 'Nedra'. p. 236 (in Russian)

NESTERENKO, G. V. and AL'MUKHAMEDOV, A. I. (1973) Geochemistry of differentiated traps (Siberian Platform). Moscow,' Nauka ", p. 198 (in Russian).

NESTERENKO, G. V., AVILOVA, N. S. and SMIRNOVA, N. P., (1964) Rare-elements in traps of the Siberian Platform. 'Geokhimiya ', no. 10, pp. 1015-1021 (in Russian).

NESTERENKO, G. V. and SMIRNOVA, N. P., (1964) Distribution of rare elements in Padun differentiated intrusion of traps. In: Geochemistry of Rare Elements in Igneous Rocks. Moscow, . Nauka ", pp, 131-141 (in Russian)·

REZNIK, I. D. and KRUGLYAKOVA, M. S., (1961) On sulfidization of the iron silicates and magnetite by the sulfur vapor and SO2. In: Proceedings of the State Institute of non-ferrous metals, no. 18, pp. 300-306 (in Russian).

RYABCHIKOV, I. D., (1972) Fugacities of sulfur and oxygen in magmatic and postmagmatic processes. In: International Geochemical Congress, v, 1, Magmatic Processes. Moscow, pp, 297-314 (in Russian).

RYABOV, V. V. and ZOLOTUKHIN, V. V., (1977) Minerals of differentiated traps. Novosibirsk., 'Nauka' p. 392 (in Russian).

SHIMA, H. andl NALDRETT, A. J., (1975) Solubility of sulfur in an ultramafic melt and the relevance of the system Fe-S-O. 'Econ. Geol. '. v. 70, no. 5, pp. 960-967.

SKINNER, B. J. and PECK, D. L., (1969) An immiscible sulfide melt from Hawaii. In: Wilson, H. D. B. ed., Magmatic Ore Deposits, a symposium: "Econ. Geol,", Mon., no. 4, pp. 310-322.

SMIRNOVA, N. P. and AL'MUKHAMEDOV, A. I., (1967) Behaviour of copper in processes of the chamber stage of trappean magma differentiation., "Geokhimiya " no. 12, pp. 1458-1467 (in Russian).

SMIRNOVA, N. P., NESTERENKO. G. V. and AL'MUKHAMEDOV, A. I., (1968) On the occurrence forms of nickel and cobalt in basic rocks. "Geokhimiya", no. 4, pp. 411-421 (in Russian).

URVANTSEV, N. N., (1973) Genetic features of formation of Norilsk copper-nickel deposits as a basis for their prospecting. 'Geologiya and Geofizika', no. 1, pp. 3-12 (in Russian).

VINOGRADOV, A. P., (1962) Average content of chemical elements in the chief-types of igneous rocks of the crust of the Earth. ' Geokhimiya', no. 7. pp. 555-571 (in Russian).

VORTSEPNEV, V. V., (1978) The formation conditions of the Talnakh ore-bearing intrusive from the microinclusion studies, 'Geologiya rudnykh mestorozhdeniy', v, 20, no. 2, pp, 64-70 (in Russian).

WAGER,L. R, VINCENT, E. A., SMALES, A. A. and BARTHCLOME, P., (1957) Sulfides in Skaergaard Intrusion, East Greenland. 'Econ. Geol.', v. 52, no. 8. pp, 855-903.

ZOLOTUKHIN, V. V., (1966) Natural sulfurization processes in basic and ultrabasic rocks. 'Akad. Nauk SSSR Doklady ', v. 167, no. 3, pp, 665-668 (in Russian).

ZOLOTUKHIN, V. V., RYABOV, V. V., VASIL'YEV, Yu. R. and SHATK0V, V. A., (1975) Petrology of Talnakh ore-bearing differentiated trap intrusion. Novosibirsk,' Nauka ', p. 436 (in Russian).

ZGLOTUKHIN, V. V. and VASIL'YEV, Yu. R., (1967) Peculiarities of formation process of ore-bearing trap intrusions of the North-West of Siberian Platform. Moscow. "Nauka ", p, 231 (in Russian).